Halogen-Free Water-Immiscible Ionic Liquids Based on Tetraoctylammonium Cation and Dodecylsulfate and Dodecylbenzenesulfonate Anions, and Their Application as Chelate Extraction Solvent
نویسندگان
چکیده
منابع مشابه
Ionic liquids with metal chelate anions.
A series of stable (air, water stable and with good thermal stability) and hydrophobic ionic liquids based upon metal chelate anions were synthesized, which were shown to be effective, mild, and easy to recycle catalysts at the same time stable solvents for the oxidation of cyclohexene.
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In the solvent extraction of metal cations into ionic liquids, use of Brønsted acid-type chelate extractants has some advantages including simplicity in controlling extraction selectivity by selecting suitable aqueous phase pH values and simple back-extraction recovery of the extracted metals using acid solutions. In this review, various fundamental and applied research on metal extraction usin...
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The proof-of-principle for the separation of metals by solvent extraction using two mutually immiscible ionic liquids is given. Cobalt was extracted from the ionic liquid 1-ethyl-3-methylimidazolium chloride to the ionic liquid trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate. A distribution ratio of 44 was obtained. Cobalt could be selectively separated from nickel, with a...
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It is shown that rare earths can be distributed between two immiscible ionic liquids, allowing the transfer of the rare earths from one ionic liquid phase to another. The ionic liquid 1-ethyl-3-methylimidazolium chloride was used as the initial feed phase and the ionic liquid trihexyl(tetradecyl)phosphonium bis(2,4,4trimethylpentyl)phosphinate (Cyphos IL 104) as the extracting phase. The rare e...
متن کاملIonic liquids as a novel solvent for lanthanide extraction.
Octyl(phenyl)-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) dissolved in an ionic liquids, 1-butyl-3-methyl-imidazolium hexafluorophosphate, greatly enhances extractability and selectivity of lanthanide cations compared to that dissolved in conventional organic solvents; further, the recovery of lanthanides extracted into ionic liquids can be accomplished using several stripping solution...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2006
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.22.199